Multifunctional Chiral Three-Dimensional Phosphite Frameworks Showing Dielectric Anomaly and High Proton Conductivity

Chair 3D Co(II) phosphite frameworks have been prepared by the ionothermal method. It belongs to chiral space group P3₂21, and the whole framework can be topologically represented as a chiral 4-connected qtz net. It shows a multistep dielectric response arising from the reorientation of Me₂-DABCO in the chiral cavities. It can also serve as a pron conductor with high conductivity, 1.71 × 10^-3 S cm^-1, at room temperature, which is attributed to the formation of denser hydrogen-bonding networks providing efficient proton-transfer pathways.