Depletion Induced Demixing and Crystallization in Binary Colloids Subjected to an External Potential Barrier

Depletion interaction plays an important role in determining the structural and dynamical properties of binary colloidal mixtures. We have investigated the effect of the attractive depletion interaction between an external potential barrier and larger species in the binary mixture on the phase behavior of a binary colloidal mixture using canonical-isokinetic ensemble molecular dynamics simulations. The demixing of the binary mixture due to this depletion interaction increases as the volume fraction increases, and a pure phase of larger particles forms in the region of the potential barrier. The local density of this pure phase is high enough that a face centered cubic crystalline domain is formed at this region. This crystalline phase diffuses perpendicular to the external potential barrier, indicating that moving crystals can be obtained in an equilibrium system. The temperature dependence of diffusivity of larger particles is non-Arrhenius and changes from sub-Arrhenius to super-Arrhenius as the volume fraction increases. This crossover from sub-Arrhenius to super-Arrhenius diffusion coincides with the crystalline formation near the potential barrier.