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Updated: Oct 8, 2025
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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
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KCs2Pb2(HCOO)2Cl5: A Lead Formate with Strong Second-Harmonic-Generation Response Obtained by an Anionic Substitution
Ziqi Zhou1,2,3, Ruibiao Fu2,4, Qirui Shui2
1College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, People's Republic of China.
Inorganic Chemistry
|December 29, 2021
Summary
Researchers synthesized a new nonlinear optical (NLO) material, KCs2Pb2(HCOO)2Cl5, using mild solvothermal methods. This material exhibits a strong second-harmonic-generation (SHG) response, making it promising for laser science applications.
Area of Science:
- Materials Science
- Solid-State Chemistry
- Photonics
Background:
- Nonlinear optical (NLO) materials are crucial for advancements in laser science and technology.
- Developing novel NLO materials with enhanced properties remains a key research objective.
Purpose of the Study:
- To synthesize and characterize a new lead formate material, KCs2Pb2(HCOO)2Cl5.
- To investigate the NLO properties and optical characteristics of the synthesized compound.
Main Methods:
- Mild mix-solvothermal synthesis.
- Anionic substitution strategy ([CH3COO] with [HCOO]).
- Systematic theoretical calculations for property analysis.
Main Results:
- Successful synthesis of KCs2Pb2(HCOO)2Cl5.
- Achieved a strong second-harmonic-generation (SHG) response (4.2 times that of KDP).
- Observed a wide transparent window (0.43-1.87 μm), large band gap (3.52 eV), and moderate birefringence (0.11@1064 nm).
Conclusions:
- The anionic substitution strategy effectively enhances NLO properties.
- KCs2Pb2(HCOO)2Cl5 is a promising candidate for NLO applications.
- This research offers a viable approach for designing new NLO crystals.
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