La/LaF₃ co-modified MIL-53(Cr) as an efficient adsorbent for the removal of tetracycline

Chromium based metal-organic framework (MIL-53(Cr)) has enormous potential in the removal of organic contaminants from aqueous solutions due to its outstanding water stability, whereas its poor adsorption capacity limits the application. In this study, La/LaF₃-MIL-53(Cr) was successfully synthesized by taking the advantages of La doping and LaF₃ encapsulation with one-step hydrothermal method. Diverse analysis tools were utilized to verify that La not only existed in the framework, but also was loaded in the pores in the form of LaF₃. The adsorption experiment results demonstrated that 0.3-La/LaF₃-MIL-53(Cr) exhibited significantly improved adsorption capacity by four times compared with the pristine MIL-53(Cr) material. XPS and FTIR revealed that the affinity of La to tetracycline was significantly stronger than that of Cr and the excellent dispersion of LaF₃ in the material may also be the cause of the increase in adsorption capacity. This study described a simple method to combine two different forms of modification and the modified material was potential for tetracycline adsorption.