Multifunctional Anthracene-Based Ni-MOF with Encapsulated Fullerenes: Polarized Fluorescence Emission and Selective...

We report an anthracene-based Ni-MOF [Ni(II) metal-organic framework, {[Ni(μ₂-L)₂Cl₂]·x(C₆H₆)·y(MeOH)} (1), L = anthracene-9,10-diylbis(methylene)diisonicotinate] whose crystal structure reveals the presence of hexagonal channels with a pore size of 1.4 nm that can accommodate guests such as C₆₀ and C₇₀. Both confocal fluorescence and Raman microscopy results are in agreement with a homogeneous distribution of fullerenes throughout the single crystals of 1. Efficient energy transfer from 1 to the fullerenes was observed, which emitted partially polarized fluorescence emission. Stronger binding between 1 and C₇₀ versus C₆₀ was confirmed from HPLC analysis of the dissolved material and provides a basis for the selective retention of C₇₀ in liquid chromatography columns packed with 1.