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Updated: Oct 7, 2025

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Triple-stranded triptycene-based metallo-supramolecular helicate displaying efficient encapsulation of bulky guest
Xu-Sheng Du1,2, Ying Han1, Chuan-Feng Chen1,2
1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. cchen@iccas.ac.cn.
Abstract:
Triple-stranded metallo-supramolecular helicates were readily constructed by achieving a coordination of the gallium(iii) cation by ligands based on 2,7- and 2,6-disubstituted triptycenes. The significance of these building blocks in the construction of helicates with the capability for guest encapsulation was also revealed.
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