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Gold clusters induce atomic-scale directional photoreactions on titanium dioxide surfaces. This study reveals anisotropic decomposition rates for benzoic acid, driven by electron conduction along specific crystal directions.

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Area of Science:

  • Surface Science
  • Photochemistry
  • Materials Chemistry

Background:

  • Titanium dioxide (TiO2) is a widely studied semiconductor photocatalyst.
  • Understanding surface reactions at the atomic scale is crucial for catalyst design.
  • Gold clusters can modify the electronic and catalytic properties of TiO2.

Purpose of the Study:

  • To investigate the influence of gold clusters on the atomic-scale anisotropy of surface carboxylate photoreactions on rutile TiO2(110).
  • To explore the role of gold clusters in directing the photoreaction of benzoic acid, a model hole-scavenger molecule.

Main Methods:

  • Scanning Tunneling Microscopy (STM) to observe surface morphology and reaction sites.
  • Density Functional Theory with onsite Coulomb interaction (DFT+U) to model electronic structure and reaction mechanisms.
  • UV/visible photoreaction experiments monitoring adsorbate depletion at room temperature.

Main Results:

  • Benzoic acid adsorption caused significant displacement of gold clusters (Au9) on TiO2 surfaces.
  • DFT calculations indicated distortion of Au9 clusters upon benzoic acid adsorption.
  • Photoreaction of benzoic acid exhibited anisotropic depletion rates, with a ~3-fold higher rate along the [001] direction compared to [110].
  • Empty sites formed elongated chains along specific crystallographic directions after photoexcitation.

Conclusions:

  • Gold clusters induce unprecedented atomic-scale anisotropy in the photoreaction of surface carboxylates on TiO2.
  • The observed anisotropy is attributed to anisotropic conduction of excited electrons along the [001] direction, leading to preferential hole accumulation and decomposition.
  • This work represents the first report of atomic-scale directionality in a semiconductor photo-induced chemical reaction.