Polydopamine coated TiO₂ nanofiber fillers for polyethylene oxide hybrid electrolytes for efficient and durable all...

The polyethylene oxide (PEO) solid electrolyte is a promising candidate for all solid state lithium-ion batteries (ASSLIBs), but its low ionic conductivity and poor interfacial compatibility against lithium limit the rate and cycling performance of the cell. Herein, the novel and efficient TiO₂@polydopamine (PDA) fillers have been synthesized by coating PDA onto the surface of the TiO₂ nanofibers, which are then incorporated into PEO matrices to form the composite electrolyte. The composite electrolyte displays a higher ionic conductivity of 4.36 × 10^-4 S cm^-1, a wider electrochemical window up to about 5 V and a higher t_Li of 0.190 at 55 °C compared to the PEO electrolyte. Additionally, the Li/composite electrolyte/Li batteries show a stable Li plating/stripping cycle performance, indicating good interfacial compatibility between the composite electrolyte and lithium. Thus, the LiFePO₄/Li ASSLIBs display a fantastic rate performance and cycling stability, and deliver superior discharge specific capacities of 153.83 and 136.45 mA h g^-1 at current densities of 0.5C and 2C, achieving good capacity retentions of 93.27% and 91.23% at 0.5C and 1C after 150 cycles, respectively. Therefore, the PEO-TiO₂@PDA composite electrolyte is a potential solid electrolyte for ASSLIBs.