Phosphate removal from actual wastewater via La(OH)₃-C₃N₄ adsorption: Performance, mechanisms and applicability

In this study, La(OH)₃ nanoparticles were immobilized on C₃N₄ to effectively restrict their aggregation and subsequently enhance the La utilization efficiency to promote phosphate adsorption. The prepared La(OH)₃-C₃N₄ nanocomposite was characterized by SEM, XRD, FTIR, XPS, BET and Zeta potential analysis. Batch and continuously-fed (fixed-bed column) experiments to assess the adsorption performance of La(OH)₃-C₃N₄ showed that the composite exhibits superior utilization efficiency, resulting to relatively quick adsorption with a short equilibrium time of 30 min. The theoretical maximum P adsorption capacity reached the 148.35 mg·g^-1, efficiency that remained unaffected by the anions and HA present. The adsorption mechanism showed stability in a wide pH range (4.0-11.0) and is considered effective even after extensive use (five-cycles). The dynamics of the adsorption capacity and the half-penetration time values were estimated by 'Thomas' and 'Yoon-Nelson' models showed that are better represented from the experimental values obtained from the fixed-bed column trial. The adsorption mechanisms were attributed to surface precipitation, electrostatic attraction, and inner-sphere complexation via ligand exchange. Furthermore, La(OH)₃-C₃N₄ demonstrated high efficiency in scavenging phosphate from both diluted and concentrated wastewater (natural pond and swine wastewater respectively). The above confirm that La(OH)₃-C₃N₄ is a promising composite material for phosphate management in aqueous environments.