Silver nanoparticles embedded 2D g-C₃N₄nanosheets toward excellent photocatalytic hydrogen evolution under visible...

Photocatalytic water splitting is considered to be a feasible method to replace traditional energy. However, most of the catalysts have unsatisfactory performance. In this work, we used a hydrothermal process to grow Ag nanoparticlesin situon g-C₃N₄nanosheets, and then a high performance catalyst (Ag-g-C₃N₄) under visible light was obtained. The Ag nanoparticles obtained by this process are amorphous and exhibit excellent catalytic activity. At the same time, the local plasmon resonance effect of Ag can effectively enhance the absorption intensity of visible light by the catalyst. The hydrogen production rate promote to 1035μmol g^-1h^-1after loaded 0.6 wt% of Ag under the visible light, which was 313 times higher than that of pure g-C₃N₄(3.3μmol g^-1h^-1). This hydrogen production rate is higher than most previously reported catalysts which loaded with Ag or Pt. The excellent activity of Ag-g-C₃N₄is benefited from the Ag nanoparticles and special interaction in each other. Through various analysis and characterization methods, it is shown that the synergy between Ag and g-C₃N₄can effectively promote the separation of carriers and the transfer of electrons. Our work proves that Ag-g-C₃N₄is a promising catalyst to make full use of solar energy.