Immobilizing chromium in tannery sludge via adding collagen protein waste: an in-depth study on mechanism

Owing to containing high fraction of organic matter, the tannery sludge seemed to be fit for composting. Actually, it was intensively harmful to the environment, due to containing chromium (Cr). So it might undergo a long time of storage until finding a proper way to dispose it. In the storage period, it would expose the surrounding environment a risk via releasing Cr. In this study, an approach was proposed to minimize the amount of released Cr, and reveal the mechanism on immobilizing Cr. Collagen protein waste (CPW) was adopted to immobilize Cr, and it was evaluated via leaching experiment. The lowest leaching concentration of Cr was 12 mg/L, meeting the limits of related standard in China (GB 5085.3-2007, Tcr < 15 mg/L). Moreover, the compositions and functional groups of the optimum sample (12 mg/L) were also characterized, confirming that the dominant functional groups cross-linking with Cr were hydroxyl (-OH), carboxyl (-COOH), and epoxy (-COC). Importantly, density functional theory (DFT) calculation was also employed, suggesting that Cr was restrained by accepting electrons from O atoms donating by functional groups.