Fluoride ions sorption using functionalized magnetic metal oxides nanocomposites: a review

Fluoride is an anionic pollutant found superfluous in surface or groundwater as a result of anthropogenic actions from improper disposal of industrial effluents. In drinking water, superfluous fluoride has been revealed to trigger severe health problems in humans. Hence, developing a comprehensive wastewater decontamination process for the effective management and preservation of water contaminated with fluoride is desirable, as clean water demand is anticipated to intensify considerably over the upcoming years. In this regard, there have been increased efforts by researchers to create novel magnetic metal oxide nanocomposites which are functionalized for the remediation of wastewater owing to their biocompatibility, cost-effectiveness, relative ease to recover and reuse, non-noxiousness, and ease to separate from solutions using a magnetic field. This review makes an all-inclusive effort to assess the effects of experimental factors on the sorption of fluoride employing magnetic metal oxide nanosorbents. The removal efficiency of fluoride ions onto magnetic metal oxides nanocomposites were largely influenced by the solution pH and ions co-existing with fluoride. Overall, it was noticed from the reviewed researches that the maximum sorption capacity using various metal oxides for fluoride sorption was in the order of aluminium oxides >cerium oxides > iron oxides > magnesium oxides> titanium oxides, and most sorption of fluoride ions was inhibited by the existence of phosphate trailed by sulphate. The mechanism of fluoride sorption onto various sorbents was due to ion exchange, electrostatic attraction, and complexation mechanism.