Ethylene dimethacrylate used as an NH₃ adsorbent with high adsorption capacity and selectivity

NH₃ molecularly imprinted polymers (NH₃-MIPs) were synthesized that could successfully separate and recover NH₃ during sludge aerobic composting; however, increased toluene usage during the adsorbent preparation incurred a high cost and severe environmental risks. The purpose of this study was to reduce toluene usage by optimizing the reagent composition of NH₃-MIPs, based on maintaining a high NH₃ adsorption capacity and selectivity. Five adsorbent groups, including NH₃-MIPs, and NH₃-Ethylene dimethacrylate adsorbents (NH₃-EGDMA) with 0%, 75%, 90%, and 100% toluene reduction efficiencies, were prepared and tested for their adsorption performance. The results showed that NH₃-EGDMA with 75% toluene reduction not only had a high NH₃ adsorption capacity (104.42 mg g^-1) but also had a high separation factor for NH₃/methyl sulfide (3121) and NH₃/dimethyl disulfide (4597). The adsorption mechanism was identified as a chemical force between NH₃ and NH₃-EGDMA with a 75% toluene reduction using the analysis of the kinetic model. This study significantly reduces NH₃ adsorbent cost as well as harm to the environment during the adsorbent preparation, which was beneficial to the popularization and application of this NH₃ adsorbent.