Broadband Optical Constants and Nonlinear Properties of SnS₂ and SnSe₂

SnS₂ and SnSe₂ have recently been shown to have a wide range of applications in photonic and optoelectronic devices. However, because of incomplete knowledge about their optical characteristics, the use of SnS₂ and SnSe₂ in optical engineering remains challenging. Here, we addressed this problem by establishing SnS₂ and SnSe₂ linear and nonlinear optical properties in the broad (300-3300 nm) spectral range. Coupled with the first-principle calculations, our experimental study unveiled the full dielectric tensor of SnS₂ and SnSe₂. Furthermore, we established that SnS₂ is a promising material for visible high refractive index nanophotonics. Meanwhile, SnSe₂ demonstrates a stronger nonlinear response compared with SnS₂. Our results create a solid ground for current and next-generation SnS₂- and SnSe₂-based devices.