Development of Antibacterial V/TiO₂-Based Galvanic Coatings for Combating Biocorrosion

Recently, TiO₂ crystals have been modified by transition-metal dopants with different physicochemical structures to attain distinguished properties. Considering the similar ionic sizes of V⁴⁺ (0.058 nm) and Ti⁴⁺ (0.061 nm), vanadium in the +4 state can be effectively incorporated into the crystal lattice of TiO₂ to tune the band gap energy by creating an impurity energy level (V⁵⁺/V⁴⁺) below the conduction band (2.1 eV) and retaining the anatase phase. In vanadium-incorporated TiO₂ (V/TiO₂), V⁴⁺ is a good dopant candidate as it can increase the lifetime of the charge carrier and reduce the electron-hole recombination rate, which results in high antibacterial activity under visible light irradiation. The present study explores the V/TiO₂-based hot-dip zinc coating with enhanced electrochemical properties and long-term stability for combating biocorrosion. All the composites and the coatings are characterized by different techniques, including X-ray diffraction, transmission electron microscopy, field emission scanning electron microscopy, energy-dispersive X-ray analysis, confocal laser scanning microscopy, optical surface profilometry, and X-ray photoelectron spectroscopy. The biofilm formation assay and the cell viability assay reveal that the tuned composition of the V/TiO₂-based hot-dip zinc coating effectively kills the adherent bacteria and inhibits biofilm formation on the surface. The high-charge-transfer resistance (225.67, 223.63, and 242.35 Ω cm²) and the high-inhibition efficiency (92.24, 92.30, and 92.02%) of the tuned composition of the V/TiO₂-based hot-dip zinc coating confirm its efficient and sustainable antibiocorrosion performance and long-term stability even after an exposure period of 21 days in different bacterial environments. With the inherent antibacterial properties and antibiocorrosion performance of the developed V/TiO₂-based hot-dip zinc coating, the mild steel substrates can find potential application in different fields, including aquatic and marine environments.