Halloysite-Based Nanorockets with Light-Enhanced Self-Propulsion for Efficient Water Remediation

Halloysite-based tubular nanorockets with chemical-/light-controlled self-propulsion and on-demand acceleration in velocity are reported. The nanorockets are fabricated by modifying halloysite nanotubes with nanoparticles of silver (Ag) and light-responsive α-Fe₂O₃ to prepare a composite of Ag-Fe₂O₃/HNTs. Compared to the traditional fabrication of tubular micro-/nanomotors, this strategy has merits in employing natural clay as substrates of an asymmetric tubular structure, of abundance, and of no complex instruments required. The velocity of self-propelled Ag-Fe₂O₃/HNTs nanorockets in fuel (3.0% H₂O₂) was ca. 1.7 times higher under the irradiation of visible light than that in darkness. Such light-enhanced propulsion can be wirelessly modulated by adjusting light intensity and H₂O₂ concentration. The highly repeatable and controlled "weak/strong" propulsion can be implemented by turning a light on and off. With the synergistic coupling of the photocatalysis of the Ag-Fe₂O₃ heterostructure and advanced oxidation in H₂O₂/visible light conditions, the Ag-Fe₂O₃/HNTs nanorockets achieve an enhanced performance of wastewater remediation. A test was done by the catalytic degradation of tetracycline hydrochloride. The light-enhanced propulsion is demonstrated to accelerate the degradation kinetics dramatically. All of these results illustrated that such motors can achieve efficient water remediation and open a new path for the photodegradation of organic pollutions.