High specific surface CeO₂-NPs doped loose porous C₃N₄for enhanced photocatalytic oxidation ability

Porous C₃N₄(PCN) is favored by researchers because it has more surface active sites, higher specific surface area and stronger light absorption ability than traditional g-C₃N₄. In this study, cerium dioxide nanoparticles (CeO₂-NPs) with mixed valence state of Ce³⁺and Ce⁴⁺were doped into the PCN framework by a two-step method. The results indicate that CeO₂-NPs are highly dispersed in the PCN framework, which leads to a narrower band gap, a wider range of the light response and an improved the separation efficiency of photogenerated charge in PCN. Moreover, the specific surface area (145.69 m²g^-1) of CeO₂-NPs doped PCN is a 25.5% enhancement than that of PCN (116.13 m²g^-1). In the experiment of photocatalytic selective oxidation of benzyl alcohol, CeO₂-NPs doped porous C₃N₄exhibits excellent photocatalytic activity, especially Ce-PCN-30. The conversion rate of benzyl alcohol reaches 74.9% using Ce-PCN-30 as photocatalyst by 8 h of illumination, which is 25.7% higher than that of pure porous C₃N₄. Additionally, CeO₂-NPs doped porous C₃N₄also exhibits better photocatalytic efficiency for other aromatic alcohols.