Element partitioning, emissions, and relative risk during disposal processes of diverse litters, fruit tree branches, and crop straws: dry distillation, incomplete combustion, and sufficient combustion

This study reports the release behaviors, enrichment characteristics, contamination level, and health risk of twenty-one elements in biomass, when dry distillation, incomplete combustion, and sufficient combustion. Results indicate that the element concentration in different kinds of biomass varies greatly. Even for the same kind of biomass, concentration in three products of dry distillation, incomplete combustion, and sufficient combustion is also different: fifteen elements (K, Ca, Mg, Al, Fe, Mn, B, Cu, Zn, Mo, Cd, Cr, Pb, Sb, Sn) have no significant difference in concentration but other six elements (As, Co, Ni, V, Na, P) are the opposite. Multivariate statistical approaches were used to assess five significant factors which affect element concentration, suggesting the contributes from biomass type, moisture content, soil, biomass age or organ, and disposal methods. Disposal methods and biomass type result in significant differences in element enrichment factor. More elements will release during sufficient combustion rather than dry distillation. The increasing of supplied oxygen during disposal process may increase the overall toxicity from elements release. The data of excess lifetime cancer risk (ELCR) suggests that Cr, Ni, Co, Cd, and Pb are the largest contributors to cancer risks during biomass application.