Tailoring the Growth of Nanosized α-Zirconium Phosphate

Nanosized α-zirconium phosphate (α-ZrP), unlike microcrystalline α-ZrP, takes less time to prepare and is synthesized directly in organic solvents. During the synthesis of nanosized α-ZrP, the heating step is critical because during which the particle growth/aggregation is ongoing. In order to explore more details of this step, extra water molecules were intentionally introduced to the ethanol gel of nanosized α-ZrP so that the evaporation of the solvent was slowed. To heat the gels at 65 °C for different periods (1-6 days), one could control with ease the synthesized α-ZrP in size, from 63 to 155 nm, and in morphology, from amorphous to highly crystalline. Furthermore, the heating step also affects the intercalated solvent and the dangling propionate groups on the edge of the nanosized α-ZrP, which could be deduced from the intercalation/exfoliation behavior of the nanocrystals. This modified synthesis method of nanosized α-ZrP offers an alternate means to tune the size and morphology of the nanosized α-ZrP for broad applications.