Layered SnS₂/porous nickel foil based Schottky junction: An excellent ammonia sensor at room temperature

In recent years, layered materials has gained immense attention in the field of gas sensing owing to their extraordinary electrical, optical and catalytic properties. Their gas sensing performance can further be improved by switching from ohmic to schottky based sensor due to exponential change of conductance in analyte environment. In most of the Schottky based gas sensor, the surface of the sensing material is covered by metal electrode which reduces the sensing performance. Herein, we have fabricated 2D SnS₂ (thickness: 5.62 ± 1.26 nm) based Schottky junction for ammonia detection operated at room temperature using porous nickel foil which allows the analyte molecule to maximize the interaction with the sensing material. We have compared the performance of the Schottky junction sensor with that of SnS₂ based ohmic sensor. The Schottky junction based sensor has 140.7 times higher response than SnS₂ based ohmic sensor at 360 ppm. The response of the sensor exhibits exponential behavior with ammonia concentration which is explained by estimated barrier height modulation from 0.83 eV (in air) to 0.69 eV (at 225 ppm). In addition, the long term stability over six months of the sensor makes it a promising candidate for practical ammonia sensor operated at room temperature.