Ag₃PO₄-based photocatalysts and their application in organic-polluted wastewater treatment

Semiconductor photocatalysis technology has shown great potential in the field of organic pollutant removal, as it can use clean and pollution-free solar energy as driving force. The discovery of silver phosphate (Ag₃PO₄) is a major breakthrough in the field of visible light responsive semiconductor photocatalysis due to its robust capacity to absorb visible light < 520 nm. Furthermore, the holes produced in Ag₃PO₄ under light excitation possess a strong oxidation ability. However, the strong oxidation activity of Ag₃PO₄ is only achieved in the presence of electron sacrifice agents. Otherwise, photocorrosion would greatly reduce the reuse efficiency of Ag₃PO₄. This review thus focuses on the structural characteristics and preparation methods of Ag₃PO₄. Particularly, the recent advances in noble metal deposition, ion doping, and semiconductor coupling, as well as methods of magnetic composite modification for the improvement of catalytic activity and recycling efficiency of Ag₃PO₄-based catalysts, were also discussed, and all of these measures could enhance the catalytic performance of Ag₃PO₄ toward organic pollutants degradation. Additionally, some potential modification methods for Ag₃PO₄ were also proposed. This review thus provides insights into the advantages and disadvantages of the application of Ag₃PO₄ in the field of photocatalysis, clarifies the photocorrosion essence of Ag₃PO₄, and reveals the means to improve photocatalytic activity and stability of Ag₃PO₄. Furthermore, it provides a theoretical and methodological basis for studying Ag₃PO₄-based photocatalyst and also compiles valuable information regarding the photocatalytic treatment of organic polluted wastewater.