Construction of Novel Bimetallic Oxyphosphide as Advanced Anode for Potassium Ion Hybrid Capacitor

Potassium ion hybrid capacitors (PIHCs) have attracted considerable interest due to their low cost, competitive power/energy densities, and ultra-long lifespan. However, the more sluggish insertion kinetics of battery-type anodes than capacitor-type cathodes in PIHCs seriously limits their practical application. Therefore, developing advanced anodes with high capacitor and suitable K⁺ intercalation is imperative and significant. A novel core-shell structure of NiCo oxide/NiCo oxyphosphide (NCOP) nanowires are designed and constructed in this study via efficient and facile strategy. Combining the merits of the core-shell structure and the massive active sites in the oxyphosphide layer, the as-prepared NCOP composites manifest highly reversible capacitors and outstanding rate capability. Meanwhile, the insertion and conversion potassium storage mechanisms of the NCOP are successfully revealed through in situ X-ray diffraction and density functional theory calculations, respectively. Furthermore, the PIHC was assembled with NCOP anode and borocarbonitride cathode, which displays a large energy density and high-power density, along with an exceptional capacity retention of ≈90% over 10 000 cycles at 1.0 A g^-1 . This work provides the anion regulation strategy for modifying the transition metal oxide and constructing the advancing electrode materials for next-generation energy storage and beyond.