High-Power Bipolar Solid-State Batteries Enabled by In-Situ-Formed Ionogels for Vehicle Applications

Employing solid electrolytes (SEs) for lithium-ion batteries can boost the battery tolerance under abusive conditions and enable the implementation of bipolar cell stacking, leading to higher cell energy and power density as well as simplified thermal management. In this context, a bipolar solid-state battery (SSB) has received ever-increasing attention in recent years. However, poor solid-solid interfacial contact within the bipolar SSB deteriorates the battery power capability, representing a technical challenge for vehicle applications. In this work, a bipolar SSB pouch cell with two cell units connected in series is demonstrated without any short circuit or current leakage. With the assistance of an in-situ-formed nonflammable ionogel at particle-to-particle interfaces, the constructed bipolar cell manifests superior power capability and can meet the engineering cold crank requirements in 0, -10, and -18 °C environments. Furthermore, the excellent tolerance of the ionogel-introduced bipolar SSB under abusive conditions was proved by folding, cutting, and burning the cells. The above salient features suggested that the developed strategy herein holds promise to advance the next-generation high-performance SSBs.