Non-Stacked γ-Fe₂O₃/C@TiO₂ Double-Layer Hollow Nanoparticles for Enhanced Photocatalytic Applications under Visible...

Herein, a non-stacked γ-Fe₂O₃/C@TiO₂ double-layer hollow nano photocatalyst has been developed with ultrathin nanosheets-assembled double shells for photodegradation phenol. High catalytic performance was found that the phenol could be completely degraded in 135 min under visible light, due to the moderate band edge position (VB at 0.59 eV and CB at -0.66 eV) of the non-stacked γ-Fe₂O₃/C@TiO₂, which can expand the excitation wavelength range into the visible light region and produce a high concentration of free radicals (such as ·OH, ·O^2-, holes). Furthermore, the interior of the hollow composite γ-Fe₂O₃ is responsible for charge generation, and the carbon matrix facilitates charge transfer to the external TiO₂ shell. This overlap improved the selection/utilization efficiency, while the unique non-stacked double-layered structure inhibited initial charge recombination over the photocatalysts. This work provides new approaches for photocatalytic applications with γ-Fe₂O₃/C-based materials.