Hydrothermal Synthesis of Hierarchical SnO₂ Nanostructures for Improved Formaldehyde Gas Sensing

The indoor environment of buildings affects people's daily life. Indoor harmful gases include volatile organic gas and greenhouse gas. Therefore, the detection of harmful gas by gas sensors is a key method for developing green buildings. The reasonable design of SnO₂-sensing materials with excellent structures is an ideal choice for gas sensors. In this study, three types of hierarchical SnO₂ microspheres assembled with one-dimensional nanorods, including urchin-like microspheres (SN-1), flower-like microspheres (SN-2), and hydrangea-like microspheres (SN-3), are prepared by a simple hydrothermal method and further applied as gas-sensing materials for an indoor formaldehyde (HCHO) gas-sensing test. The SN-1 sample-based gas sensor demonstrates improved HCHO gas-sensing performance, especially demonstrating greater sensor responses and faster response/recovery speeds than SN-2- and SN-3-based gas sensors. The improved HCHO gas-sensing properties could be mainly attributed to the structural difference of smaller nanorods. These results further indicate the uniqueness of the structure of the SN-1 sample and its suitability as HCHO- sensing material.