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Published on: February 11, 2016
Visible Light-Induced Aerobic Oxidative Dehydrogenation of C-N/C-O to C=N/C=O Bonds Using Metal-Free Photocatalysts:
Alejandro Torregrosa-Chinillach1, Rafael Chinchilla1
1Department of Organic Chemistry, Faculty of Sciences, Institute of Organic Synthesis (ISO), University of Alicante, Apdo. 99, 03080 Alicante, Spain.
Abstract:
Performing synthetic transformation using visible light as energy source, in the presence of a photocatalyst as a promoter, is currently of high interest, and oxidation reactions carried out under these conditions using oxygen as the final oxidant are particularly convenient from an environmental point of view. This review summarizes the recent developments achieved in the oxidative dehydrogenation of C-N and C-O bonds, leading to C=N and C=O bonds, respectively, using air or pure oxygen as oxidant and metal-free homogeneous or recyclable heterogeneous photocatalysts under visible light irradiation.
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