A high efficiency water hydrogen production method based on CdS/WN composite photocatalytic

Based on the strategy that electrocatalysts can be used as additives to improve the performance of photocatalysts, and the unique metalloid properties of tungsten nitride (WN), it can form a Schottky junction with the semiconductor at the heterogeneous interface to improve the photocatalytic performance of semiconductor catalysts. In this paper, WN with excellent electrical conductivity was selected as a new noble-metal-free co-catalyst to improve the photoreduction hydrogen (H₂) evolution performance of CdS nanoparticles (NPs). Firstly, WN nanosheets were prepared by sol-gel method; then, a novel and noble-metal-free heterojunction photocatalyst, which is CdS NPs deposited on the surface of WN, was successfully fabricated via one-pot solvothermal method. Under visible light irradiation, the H₂ production rate of the WN/CdS composite catalyst is 24.13 mmol/g/h, which is 9.28 times that of pure CdS NPs. The observably boosted H₂ generation activity could be ascribed to the broadened visible-light absorption and intimate interfacial contact between CdS NPs and WN engenders Schottky junction. This study provides a novel and cost-effective approach for designing efficient noble-metal-free photocatalysts and improving H₂ evolution activity of CdS under visible-light-driven photocatalytic water splitting.