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Updated: Oct 5, 2025

Spatial Separation of Molecular Conformers and Clusters
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Infrared Spectra of Hydrogen-Bonded Molecular Complexes Under Spatial Confinement

Marta Chołuj1, Josep M Luis2, Wojciech Bartkowiak1

  • 1Faculty of Chemistry, Wroclaw University of Science and Technology, Wrocław, Poland.

Frontiers in Chemistry
|January 24, 2022
PubMed
Summary

Spatial confinement significantly alters molecular vibrational spectra. This study reveals how external potentials impact infrared (IR) spectroscopy of hydrogen-bonded complexes, affecting frequencies and intensities.

Keywords:
harmonic oscillator potentialhydrogen-bonded complexesinfrared spectrum (IR)spatial confinementvibrational transition intensity

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