The CO2 absorption and desorption analysis of tri-solvent MEA + EAE + AMP compared with MEA + BEA + AMP along with
Huancong Shi1,2,3, Xiaofang Cheng4, Jiacheng Peng4
1Department of Environmental Science and Engineering, University of Shanghai for Science and Technology, Shanghai, 200093, People's Republic of China. hcshi@usst.edu.cn.
Abstract:
The slow kinetics of CO2 absorption and high energy cost of CO2 desorption were the main challenges for CO2 capture technology. To overcome these drawbacks, a novel tri-solvent MEA (monoethanolamine) + EAE (2-(ethylamino)ethanol) + AMP (2-amino-2-methyl-1-propanol) was prepared at different amine concentrations of 0.1 ~ 0.5 + 2 + 2 mol/L. The CO2 absorption and desorption experiments were conducted on MEA + EAE + AMP and their precursor MEA + EAE to evaluate the absorption-desorption parameters. Results demonstrated that the optimized concentrations of the bi-blend were 0.2 + 2 mol/L for absorption and 0.4 + 2 mol/L for desorption. For the tri-solvent, the optimized concentration was 0.2 + 2 + 2 mol/L, consistently for both abs-desorption sides. Compared with tri-solvent of MEA + BEA + AMP, MEA + EAE + AMP proved better in absorption but poorer in desorption, while its CO2 loading of operation line was 0.35 ~ 0.70 mol/mol, higher than that of 0.30-0.60 mol/mol MEA + BEA + AMP. These results led to another tri-solvent candidate of amine solvents in an industrial pilot plant.
