Functionalizing biochar by Co-pyrolysis shaddock peel with red mud for removing acid orange 7 from water

Biochar modification by metal/metal oxide is promising for improving its adsorption capability for contaminants, especially the anions. However, conventional chemical modifications are complicated and costly. In this study, novel Fe/Fe oxide loaded biochars (RMBCs) were synthesized from a one-step co-pyrolysis of red mud (RM) and shaddock peel (SP), and their potential application for removing anionic azo dye (acid orange 7, AO7) from the aqueous environment was evaluated. Fe from red mud was successfully loaded onto biochars pyrolyzed at 300-800 °C, which presented from oxidation form (Fe₂O₃) to the reduction forms (FeO and Fe⁰) with increasing pyrolysis temperature. The RMBC produced at 800 °C with RM:SP mass ratio of 1:1 (RMBC800_1:1) exhibited the best capability for AO7 removal (∼32 mg/g), attributed to both adsorption and degradation. The higher surface area of RMBC800_1:1 and its greater affinity for AO7 led to the higher adsorption. In addition, RMBC800_1:1-induced degradation of AO7 was another key mechanism for AO7 removal. The reduction forms of Fe (FeO or Fe⁰) in RMBC800_1:1 may provide electrons for breaking down the azo bond in AO7 molecules and result in degradation, which is further enhanced in acid conditions due to the participation of readily release of Fe²⁺ and the available H⁺ in AO7 degradation. Furthermore, RMBC800_1:1 can be easily separated from the treated water by using magnetic field, which significantly benefits its separation in wastewater treatment.