A rhodamine based dual chemosensor for Al³⁺ and Hg²⁺: Application in the construction of advanced logic gates

A rhodamine-based compound (RBO), which has been constructed from the reaction between N-(rhodamine-6G)lactam-ethylenediamine and 2,1,3-benzoxadiazole-4-carbaldehyde, is reported here as a selective chemosensor for both Al³⁺ and Hg²⁺ ions in 10 mM HEPES buffer in water:ethanol (1:9, pH = 7.4). Absorption intensity of RBO increases considerably at 528 nm with these cations. It shows fluorescence enhancement at 550 nm by 1140- and 524-fold in the presence of Al³⁺ and Hg²⁺, respectively. LOD has been determined as 6.54 and 16.0 nM for Al³⁺ and Hg²⁺, respectively. Quantum yield and lifetime of RBO enhances with these metal ions. Fluorescence intensity of Al-probe complex or Hg-probe complex is quenched in the presence of fluoride or sulfide ion, respectively, opening a path for the construction logic gates. DFT analysis has been used to understand the spectral transitions. We have constructed a systematic development from single to five inputs complex circuit, and for the first time a time dependent five input complex logic circuit is reported herein.