Singlet oxygen-dominated electrocatalytic oxidation treatment for the high-salinity quaternary ammonium compound...

The widespread application of quaternary ammonium compounds (QAC) has posed a serious hazard to the environment and human being, and high concentration of Cl^- in QAC wastewater may further increase the difficulty of pollutants elimination. In this study, such a QAC wastewater under high salinity conditions was chosen as the target, the prepared Ti/(Ru_xIr_y)O₂ anode exhibited favorable catalytic performance for the oxidation and mineralization of QAC under high salinity conditions. Increasing the Ru/Ir ratio of Ti-based electrode coating also slightly promoted the inner catalytic capacity. The combination of electron paramagnetic resonance (EPR) and quenching experiments indicates that ¹O₂ served as a main reactive specie in the Ti/(Ru_xIr_y)O₂ electrooxidation system. The increase of pH could decrease the removal efficiency of QAC for the reduced ¹O₂ yield, and the rise of Cl^- concentration could favor the QAC oxidation, and Cl^- was a better electrolyte to promote the oxidation of organic contaminants when compared to Na₂SO₄ or Na₂CO₃. Additionally, the conversion pathway of the model pollutant was tentatively investigated, the results demonstrated that there were almost no halogenated final products residual by electrocatalytic oxidation with Ti/(Ru_xIr_y)O₂ anode. This study not only elucidate the reaction mechanism of Ti/(Ru_xIr_y)O₂ anode electrocatalytic oxidation of high salinity QAC wastewater, but also may provide an efficacious and eco-friendly method for the treatment of high salinity QAC wastewater.