New advanced oxidation progress with chemiluminescence behavior based on NaClO triggered by WS₂ nanosheets

As one integral part of coping strategies for addressing water pollution, advanced oxidation progresses (AOPs) get enormous attentions in recent years. However, the complex synthesis and high cost of H₂O₂ and K₂S₂O₈ hampered their developments. Herein, a novel AOP with the chemiluminescence (CL) property based on economic NaClO and WS₂ nanosheets was proposed to achieve efficient decomposition of organic pollutants. In this AOP, WS₂ nanosheets exhibited a dual-function feature of the catalyst and energy acceptor. It demonstrated that the reaction order of WS₂ nanosheets was equal to 0.8271 and enormous singlet oxygen (¹O₂),·ClO and hydroxyl radical (·OH) were generated in rhodamine B (RhB) degradation process. Interestingly, a strong CL emission was observed and reflected the relative concentration of ¹O₂ and·OH for adjusting the oxidizing capability in WS₂ nanosheets-NaClO system. Through a series of degradation tests, RhB, methylene blue (MB), p-nitrophenol and phenol were decomposed and the degradation efficiency of over 90% was achieved. Therefore, this study not only builds a chemiluminescent AOPs to eliminate organic pollutants, but also broadens the applications of WS₂ nanomaterials and CL in environmental field.