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Updated: Oct 4, 2025

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
A supported Cr-Cr sextuple bond in an all-metal cluster
Xingman Liu1, Min Zhang2, Yingtao Liu1
1School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China. liuyt@nxu.edu.cn.
Abstract:
Herein, we report a distinct Cr-Cr sextuple bond with an ultra-short length stabilized by equatorial alkali metals. Bonding analyses indicate that the two desired 4p-pi bonds failed to be formed but the bonding strength is enhanced due to the introduction of alkali metals, weakening the Cr-Cr 4s-4s effect. The Cr-Cr sextuple bond comprises five explicit 3d-3d overlaps and another delocalized σ bond.
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