Behavior Evolution of Droplets Suspended in Castor Oil under Alternating Current Electric Field

Electric fields, which can promote the approach of droplets and break the liquid film, are extensively used in the separation of the water phase in water-in-oil emulsions. However, there is an evolution of droplet behavior under an electric field. After the two droplets meet with each other, the electric force becomes undesirable, which would even cause breakup of the merged droplet. When the electric field strength E reaches a particular value, the final behavior of droplets is made, which goes against coalescence, and there are lots of behavior evolution types. Several research studies have studied on whether droplets coalesce and the critical condition, but few works have focused on the classification and mechanism of non-coalescence behaviors. In this paper, the behavior evolution of two single droplets suspended in castor oil under an alternating current electric field is studied by a high-speed camera. Six distinct behavior evolution modes are observed and summarized: coalescence, bounce, partial coalescence, partial rupture, coalescence-rupture, and rupture. The behavior evolution mode is influenced by the initial separation distance s₀ between droplets and the electric field strength. Moreover, there exist critical electric field strengths among different behavior evolution modes. As E gradually increases, two water droplets go through coalescence, partial coalescence, and coalescence-rupture in sequence when s₀ is small and coalescence, bounce, partial rupture, and rupture when s₀ is large. The mechanisms of behavior evolution are revealed by investigating the confrontation between electric force and capillary force in the condition with liquid bridge or pressure difference from the surrounding fluid and electric force in the condition without a liquid bridge. In addition, a cone-dimple mode of water droplets in castor oil is found, demonstrating the rationality of electric force theory.