The relationship between volcanism and global climate changes in the Tropical Western Pacific over the...

Volcanoes are a significant component of the Earth system, influencing the interaction between oceans and the atmosphere over large spatial and temporal scales. Being a volcanically dynamic region, the Tropical Western Pacific (TWP) can significantly impact variations in global climate. However, high-resolution continuous records of volcanic activity in this region are lacking, resulting in significant uncertainties regarding the coupling between the deep earth, climate changes, and atmospheric CO₂ in the TWP. To address this issue, mercury (Hg) levels, isotopic compositions, and Hg/total organic carbon (Hg/TOC) ratios were determined at site U1486 to track volcanic activity throughout the mid-Pleistocene transition (MPT) from 1.3 Myr to 0.6 Myr. Our results of anomalously high Hg concentrations and Hg/TOC ratios provide evidence of time-varying volcanism throughout the MPT. Mercury isotopes in the Hg-enriched sediments were characterized by near-zero Δ¹⁹⁹Hg values, which is consistent with volcanism acting as the primary source of Hg to the sediments. Spectral analysis of the Hg/TOC ratio showed significant periodicity at ~100 kyr and ~ 23 kyr as well as a weaker signal at ~41 kyr consistent with Milankovitch cycles. A cross spectral analysis of Hg/TOC and the LR04 δ¹⁸O stack record suggests that the peak in volcanism lags the temperature minimum by ~6 kyr, and occurs prior to the δ¹⁸O minimum known as the glacial termination by ~14 ± 2 kyr. The records of volcanic activity in this site are also consistent with a prominent rise in atmospheric CO₂ and negative excursion of benthic carbon isotopes throughout the MPT. This study provides direct sedimentary evidence in the TWP of the feedback between volcanic activity, climate change and atmospheric CO₂.