Magnetic γ-Fe₂O₃/ZIF-7 Composite Particles and Their Application for Oily Water Treatment

Crude oil spills are about global challenges because of their destructive effects on aquatic life and the environment. The conventional technologies for cleaning crude oil spills need to study the selective separation of pollutants. The combination of magnetic materials and porous structures has been of considerable interest in separation studies. Here, γ-Fe₂O₃/ZIF-7 structures were prepared by growing a ZIF-7 layer onto supermagnetic γ-Fe₂O₃ nanoparticles with an average size of 18 ± 0.9 nm in situ without surface modification at low temperatures. The product composite particles were characterized using X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, vibrating sample magnetometry, and N₂ adsorption/desorption isotherms. The analyses revealed a time growth-dependent ZIF-7 rod thickness with abundant nanocavities. The γ-Fe₂O₃/ZIF-7 surface area available for sorption (647 m²/g) is ∼12-fold higher than that of the γ-Fe₂O₃ nanoparticles. Moreover, the crystal structure of γ-Fe₂O₃ remained essentially unchanged following ZIF-7 coating, whereas the superparamagnetism declined depending on the coating time. The γ-Fe₂O₃/ZIF-7 particles were highly hydrophobic and selectively and rapidly (<5 min) sorbed crude oil and other hydrocarbon pollutants from water. As high as 6 g/g of the hydrocarbon was sorbed by the γ-Fe₂O₃/ZIF-7 particles immersed into the hydrocarbon. A coefficient of determination, R ₂ ², consistently >0.96 at all pollutant concentrations suggested a pseudo-second-order sorption kinetics. The thermal stability and 15 cycles of use and reuse confirmed a robust γ-Fe₂O₃/ZIF-7 sorbent.