Electrospun Liquid-Infused Membranes for Emulsified Oil/Water Separation

From an environmental perspective, microfiltration membranes are attractive for the separation of emulsified oils from contaminated water. However, fouling of the membrane is a major drawback of the technology. "Liquid-infused membranes" (LIMs) have the potential to eliminate membrane fouling. Here, we demonstrate the practical application of LIMs for the separation of oil from a stable oil-in-water emulsion and characterize their resistance to fouling. The base membrane is an electrospun nonwoven fibrous layer of the fluorinated copolymer poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP). The surface energy of the PVDF-co-HFP fibers was lowered by the covalent attachment of a fluorinated silane (PFOCTS), and then, the membrane was infused with a perfluoropolyether. The membrane was then challenged with model emulsions of dodecane in water in a cross-flow configuration. This PFOCTS-modified LIM showed better infused liquid stability, permeation selectivity, higher permeate flux than the unmodified LIM, and better anti-fouling properties than the bare membrane without infused liquid. We also examine the mechanism for transport of the dispersed oil phase through the liquid-infused membrane. We find a linear relationship between the dodecane flux and dodecane concentration in the feed and a higher dodecane flux through the PFOCTS-modified membrane than the unmodified one, which suggests that the capture of dodecane droplets from the feed plays an important role in determining the overall rate of permeation. Other factors such as lower viscosity of the infused liquid, larger pore size, and higher operating pressure also improved the permeate flux through the LIMs. Overall, this work provides some guidelines on the design of composite membranes comprising infused liquids and the choice of operating conditions for the filtration process.