Molecular Solar Thermal Systems towards Phase Change and Visible Light Photon Energy Storage

Molecular solar thermal (MOST) systems have attracted tremendous attention for solar energy conversion and storage, which can generate high-energy metastable isomers upon capturing photon energy, and release the stored energy as heat on demand during back conversion. However, the pristine molecular photoswitches are limited by low storage energy density and UV light photon energy storage. Recently, numerous pioneering works have been focused on the development of MOST systems towards phase change (PC) and visible light photon energy storage to increase their properties. On the one hand, the strategy of simultaneously capturing isomerization enthalpy and PC energy between solid and liquid can not only offer high latent heat, but also promote the development of sustainable energy systems. On the other hand, the efficient photon energy storage in the visible light range opens a tremendously fascinating avenue to fabricate MOST systems powered under natural sunlight. Here, the recent advances of MOST systems towards PC and visible light photon energy storage are systematically summarized, the most promising advantages and current challenges are analyzed, and emerging strategies and future research directions are proposed.