Smart Synthesis of Hollow Microporous Organic Capsules with a Polyaniline Modified Shell

In this work, novel hypercrosslinked polymer-based hollow microporous organic capsules with a polyaniline (PANI)-modified shell (PANI@S-HMOCs) are prepared by in-situ polymerization of aniline in the porous structure of the sulfonated hollow microporous organic capsules (S-HMOCs). PANI@S-HMOC1, PANI@S-HMOC2, and PANI@S-HMOC3 are made by adjusting S-HMOCs and aniline weight ratios of 4:1 and 3:1, and 2:1, respectively. The characterizations of PANI@S-HMOCs demonstrate that electrostatic interaction between aniline and sulfonic acid groups plays an important role in encapsulating PANI in the pores of the shell. The content of PANI shows an evident effect on the porosity of PANI@S-HMOCs, and an appropriate polyaniline loading amount may increase the surface area. PANI@S-HMOC1 and PANI@S-HMOC2 have higher BET surface areas (529 and 503 m² g^-1 ) than S-HMOCs (424 m² g^-1 ), but PANI@S-HMOC3 has lower BET surface area (380 m² g^-1 ). Based on the structural and textural features, PANI@S-HMOC2 shows good adsorption performance for Cr(VI) from aqueous media (156 mg g^-1 , pH = 2, and 27 mg g^-1 , pH = 7).