BASIC: A Comprehensive Model for SO Formation Mechanism and Optimization in Municipal Solid Waste (MSW) Combustion

Municipal solid waste (MSW) incineration is one of the main techniques currently used for waste to energy (WTE) conversion in China. Although the sulfur content in MSW is lower than that in coal, its emission cannot be neglected due to environmental pollution, malodor, health problems, and global climate change. Therefore, it is particularly important to effectively predict and control the sulfur pollutants. In this study, a comprehensive model was developed and coupled with the full combustion process bed model bulk accumulated solids incineration code (BASIC) to investigate the formation and transformation processes of sulfur in MSW incineration. The submodels of the four stages in the MSW combustion processes; governing equations of mass, momentum, and energy conservation; and various chemical reactions were included in the model. Based on this model, the effects of different parameters on the formation of sulfur pollutants during the incineration process were studied under different operating conditions. The study finds that for SO formation, initial temperature, primary air volume, and material particle size have significant impacts, whereas pressure shows a less significant effect. This article also considers H₂S, COS, and CS₂ formation under different conditions. An optimization study was performed to reduce SO pollutants.