Spatial distribution and migration of ^239+240Pu in Chinese soils

The migration of radionuclides is a critical threat to the soil and groundwater environment. This study investigates highly radiological toxic ^239+240Pu in 647 surface soils and 66 soil cores in China. First, the spatial distributions of ^239+240Pu activities and ²⁴⁰Pu/²³⁹Pu ratios are presented in Chinese surface soils. Second, four different types of vertical distribution of ^239+240Pu, namely 45.4%, 40.9%, 9.1% and 4.5% of Chinese soil cores proportions are integrated using statistical analysis. Furthermore, different soil types are accompanied by different ^239+240Pu vertical distributions, which relate closely to the ^239+240Pu migration. Finally, based on the Convection Dispersion Equation (CDE) model, the present work find that the apparent convection velocities of ^239+240Pu are ranging from 0.00032 ± 0.00031 cm a^-1 to 0.473 ± 0.083 cm a^-1. As shown by the four typical vertical activity distribution of ^239+240Pu in soil cores, the deepened activity maximum value position of ^239+240Pu implies a fast migration rate or apparent convection velocity. This study, for the first time, suggests a significant linear correlation (R² = 0.847) between the depth of ^239+240Pu maximum value (cm) and the apparent convection velocity (v, cm a^-1). We hypothesize that v usually does not exceed 0.5 cm a^-1 in the CDE model. A significant linear correlation is also identified between apparent dispersion coefficient (D, cm² a^-1) and v² in Chinese soil cores from the CDE model. It will provide an important reference for harmful heavy metal migration research in the future.