Related Experiment Video
Updated: Oct 3, 2025
Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Tying Covalent Organic Frameworks through Alkene Metathesis and Supported Platinum as Efficient Catalysts for
Defa Gu1, Guangwen Li2, Yushan Liu3
1School of Chemistry, Beihang University, Bejing 100191, China.
Abstract:
Recently there has been a great interest in covalent organic frameworks due to their fascinating properties. Current approaches to improve their hydrolytic stability mainly rely on the transformation of the dynamic bonds into strong and irreversible bonds, but these approaches also reduce the versatility of the frameworks. Herein, we would like to demonstrate a solution to this dilemma by forming hierarchical bonds through olefin metathesis to produce highly stable COFs. Our approach allows unprecedented opportunities for post-modification of the inner space through the dynamic imine bonds while maintaining the integrity of the framework. Specifically, we demonstrate an amorphous-to-crystalline transformation. In addition, the porosity can be enhanced by up to 70% after full removal of the amine subunits. Overall, our work provides a new direction for the generation of highly stable while still versatile COFs. Meanwhile, platinum(II) complexes can be supported on BHU-2 (Pt@BHU-2) or BHU-2-Oxidate(Pt@BHU-2-Oxidate) as efficient catalysts for hydrosilylation.
More Related Videos
12:08Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
10:19Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
Published on: July 18, 2017
Related Concept Videos
02:24Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
02:13Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
02:17Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
02:47Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
02:44Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
02:40Alkynes to Aldehydes and Ketones: Acid-Catalyzed Hydration
Analogous to alkenes, alkynes also undergo acid-catalyzed hydration. While the addition of water to an alkene gives an alcohol, hydration of alkynes produces different products such as aldehydes and ketones.