Dependence of Electrical Conductivity on Phase Morphology for Graphene Selectively Located at the Interface of...

Conductive composites of polypropylene (PP) and polyethylene (PE) filled with thermally reduced graphene oxide (TRG) were prepared using two different processing sequences. One was a one-step processing method in which the TRG was simultaneously melt blended with PE and PP, called TRG/PP/PE. The second was a two-step processing method in which the TRG and the PP were mixed first, and then the (TRG/PP) masterbatch was blended with PE, called (TRG/PP)/PE. The phase morphology and localization of the TRG in TRG/PP/PE and (TRG/PP)/PE composites with different PP/PE compositions were observed by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The TRG was found to be selectively dispersed in the PE phase of the TRG/PP/PE composites, resulting in a low percolation threshold near 2.0 wt%. In the (TRG/PP)/PE composites, the TRG was selectively located at the PP/PE blend interface, resulting in a percolation threshold that was lower than 1.0 wt%. With the addition of 2.0 wt% TRG, the (TRG/PP)/PE composites exhibited a wide range of electrical conductivities at PP/PE weight ratios of 10 w/90 w to 80 w/20 w. Moreover, electrical and rheological measurements of the composites revealed that the co-continuous phase structure is the most efficient candidate for the fabrication of conductive composites.