Rheological Considerations in Processing Self-Reinforced Thermoplastic Polymer Nanocomposites: A Review

The present review relates to the field of nanocomposite materials comprising a thermoplastic nanofibrillar phase dispersed in a matrix that is also thermoplastic. The fact of forming the nanofibrillar phase in situ during melt processing gives it the role of a reinforcing nanofiller for thermoplastic materials. This paper discusses the major factors influencing the formation of self-reinforced nanofibrillar polymer composite (NFC) materials throughout manufacturing steps. More specifically, the rheological considerations allowing the prediction of the in situ nanofibrillation during melt blending and post-processing as well as the methods of production of these polymer nanocomposites are described. The major challenges related to the future development in the field of NFCs are addressed. The concept of self-reinforced nanofibrillar polymer materials shows great potential in lightweight eco-design processes and represents a new approach to polymer nanocomposite recycling for a variety of industrial applications.