Novel Fabrication of Silver-Coated Copper Nanowires with Organic Compound Solution

Copper nanowires and Cu-Ag nanowires have various potential applications, such as transparent conductive film, flexible electronics, and conductive filler. In this study, we developed a new green fabrication method for silver-coated copper nanowires using methylsulfonylmethane (DMSO₂), which is an environmentally friendly chemical at the food-grade level, to replace toxic chemicals, including ammonia, in the silver coating process. Copper nanowires were synthesized under various reaction temperatures and concentrations of hydrazine (N₂H₄), ethylenediamine (EDA), sodium hydroxide (NaOH), and copper precursor. The reaction temperature higher than 70 °C caused the oxidation of copper products and evaporation of the sample solution. The optimal conditions to synthesize copper nanowires more than 18 µm in length and 25-45 nm in diameter were determined: 9 M of NaOH, 50 µL of EDA, 17 mM of CuCl₂, 5.7 mM of N₂H₄, and 70 °C reaction temperature. Cu-Ag nanowires, which have about a 12 nm thick silver shell, were successfully fabricated at room temperature under 1 mM of silver nitrate (AgNO₃) and 1 wt % of DMSO₂. Synthesis conditions for copper and silver-coated copper nanowires have been optimized.