CO₂ Absorption Mechanism by the Deep Eutectic Solvents Formed by Monoethanolamine-Based Protic Ionic Liquid and...

Deep eutectic solvents (DESs) have been widely used to capture CO₂ in recent years. Understanding CO₂ mechanisms by DESs is crucial to the design of efficient DESs for carbon capture. In this work, we studied the CO₂ absorption mechanism by DESs based on ethylene glycol (EG) and protic ionic liquid ([MEAH][Im]), formed by monoethanolamine (MEA) with imidazole (Im). The interactions between CO₂ and DESs [MEAH][Im]-EG (1:3) are investigated thoroughly by applying ¹H and ¹³ C nuclear magnetic resonance (NMR), 2-D NMR, and Fourier-transform infrared (FTIR) techniques. Surprisingly, the results indicate that CO₂ not only binds to the amine group of MEA but also reacts with the deprotonated EG, yielding carbamate and carbonate species, respectively. The reaction mechanism between CO₂ and DESs is proposed, which includes two pathways. One pathway is the deprotonation of the [MEAH]⁺ cation by the [Im]^- anion, resulting in the formation of neutral molecule MEA, which then reacts with CO₂ to form a carbamate species. In the other pathway, EG is deprotonated by the [Im]^-, and then the deprotonated EG, HO-CH₂-CH₂-O^-, binds with CO₂ to form a carbonate species. The absorption mechanism found by this work is different from those of other DESs formed by protic ionic liquids and EG, and we believe the new insights into the interactions between CO₂ and DESs will be beneficial to the design and applications of DESs for carbon capture in the future.