Universal p-Type Doping via Lewis Acid for 2D Transition-Metal Dichalcogenides

Developing spatially controlled and universal p-type doping of transition-metal dichalcogenides (TMDs) is critical for optoelectronics. Here, a facile and universal p-doping strategy via Sn⁴⁺ ions exchanging is proposed and the p-doping of PdSe₂ is demonstrated systematically as the example. The polarity of PdSe₂ can be modulated from n-type to bipolar and p-type precisely by changing the concentration of SnCl₄ solution. The modulation effectively reduces the electron concentration and improves the work function by ∼72 meV. In addition, the solution-processable route makes the spatially controlled doping possible, which is demonstrated by constructing the lateral PdSe₂ p-n homojunction with rectification behavior and photovoltaic effect. This p-doping method has been further proved in modulating various TMDs including WSe₂, WS₂, ReSe₂, MoSe₂, MoTe₂, and PtSe₂. This spatially controlled and universal method based on Sn atoms substitution realizes p-type doping of TMDs.