Carbon nanotube supported oriented metal organic framework membrane for effective ethylene/ethane separation

Zeolitic imidazolate framework 8 (ZIF-8) is effective for C₃H₆/C₃H₈ separation because of the "sieving effect" of a six-membered (6-M) window. Here, we demonstrate that ZIF-8 is a versatile material that could effectively separate C₂H₄ from C₂H₆ via its 4-M window along the <100> direction. We established a facile and environmentally friendly carbon nanotube (CNT)-induced oriented membrane (CNT-OM) approach to fabricate a {100}-oriented ZIF-8 membrane (100-M). In this approach, 2-methyimidazole was anchored onto the CNT surface followed by 3-hour in situ growth in aqueous solution at room temperature. The obtained 100-M, whose 4-M window is aligned along the transport pathway, showed ~3 times higher C₂H₄/C₂H₆ selectivity than a randomly oriented membrane. Thus, this work demonstrates that the membrane orientation plays an important role in tuning selectivity toward different gas pairs. Furthermore, 100-M exhibited excellent mechanical stability that could sustain the separation performance after bending at a curvature of ~109 m^-1.