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Iron pentacarbonyl ligands on silver scorpionates

Guocang Wang1, Anurag Noonikara-Poyil1, Israel Fernández2

  • 1Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas 76019, USA. dias@uta.edu.

Chemical Communications (Cambridge, England)
|February 17, 2022
PubMed
Summary

Fluorinated ligands stabilize silver(I) with iron pentacarbonyl. The silver-iron bond is primarily electrostatic, influenced by sigma-donation and backbonding, tunable via scorpionate groups.

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